Temperature Controlled of Self-Oscillating for Polymer Chains Induced by BZ Reaction with Fe(phen)3 Catalyst


  •  Jie Ren    
  •  Mengqi Yao    
  •  Guangcheng Zhang    
  •  Jinfen Gu    
  •  Li Tao    
  •  Wu Yang    

Abstract

The polymer chain with Fe(phen)3-catalyzed was demonstrated to occur self-oscillation phenomenon in BZ reaction system. The self-oscillation polymer composed of N-isopropylacrylamide and Fe(phen)3 catalyst moiety, which were synthesized by radical polymerization. It was found that the self-oscillation parameters (induction period, Ti, oscillation period, Tp and amplitude) could be regulated by subtle changes of temperature. It can be well explained by the FKN mechanism.



This work is licensed under a Creative Commons Attribution 4.0 License.
  • ISSN(Print): 1927-0585
  • ISSN(Online): 1927-0593
  • Started: 2012
  • Frequency: quarterly

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