Synthesis of [2] Rotaxanes Derived from Host-Guest Interaction


  •  Hemat Dardeer    
  •  Mamdouh Hassan    

Abstract

Interlocked molecules such as rotaxanes and catenanes have a lot of studies in last twenty years. Due to their unique structures and properties. In this work [2] rotaxanes (A), (B), and (C) containing of α, β and/or γ cyclodextrins have been prepared respectively. Construction of these compounds depend on forming stable inclusion complexes between cyclodextrin and hexamethylenediamine which ended with a bulky group 9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic anhydride. The chemical structure of synthesized inclusion complexes can be confirmed by spectral analysis and physical properties.



This work is licensed under a Creative Commons Attribution 4.0 License.
  • ISSN(Print): 1916-9698
  • ISSN(Online): 1916-9701
  • Started: 2009
  • Frequency: semiannual

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