Study of Intermolecular Interactions of Binary Liquid Mixtures by Measuring Intensive Macroscopic Properties at (303.15, 313.15 and 323.15) K and at Ambient Pressure

T.R Kubendran, R. Baskaran


Measurements of thermodynamic and transport properties have been adequately employed in understanding the nature of molecular systems and physico-chemical behavior in liquid mixtures. These properties are important from practical and theoretical point of view to understand liquid theory. In the present study density (?) and viscosity (?), have been measured for a binary liquid mixture of Diacetone alcohol with benzene and chlorobenzene, over the entire composition range at 303.15 K, 313.15 K and 323.15 K and the evaluation of different excess properties. The viscosity values and excess values were fitted to respective models. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The molecular interactions existing between the components and comparison of liquid mixtures were also discussed.

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