Abstract

Modeling of sorption data is essential for characterizing retention of heavy metals by the soil matrices as well as to predict the fate of heavy metals in the environment. We carried out a study to evaluate adsorption characteristics of metallic ions (Cr³⁺, Pb²⁺ and Cu²⁺) as sole sorbates as well as in coexistence onto clay extracts of Vertic-Luvisol and Ferralic-Arenosol, the generally under-researched yet wide-spread semi-arid soils. Additionally, sorption kinetics of these heavy metals was evaluated in these soils. Equilibrium sorption data for both non-competitive and competitive metal systems were found to obey the Langmuir isotherm. Overall metal loading capacity was higher in Vertic-Luvisol than Ferralic-Arenosol whereas metal-wise affinity to binding sites favoured sorption of Cr³⁺ over Pb²⁺ and Cu²⁺ in that order. Contrary to the hypothesis of this study, the preferential sorption process was found to be driven by cationic properties as opposed to soil properties. Adsorption of metallic ions onto soils was significantly reduced in competitive systems than non-competitive systems, a phenomenon attributable to the antagonistic effects of coexisting species. Cr³⁺ suppressed sorption of Pb²⁺ and Cu²⁺ on both soils as validated by the competitive adsorption capacity ratios which were < 1 in all instances where Cr³⁺ coexisted with either one of Pb²⁺ or Cu²⁺. The adsorption kinetics of metal ions in both soils followed the pseudo-second-order rate law, suggesting chemical sorption as the rate-limiting step of the adsorption process.

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