Direct Passerini Reaction of Aldehydes, Isocyanides, and Aliphatic Alcohols Catalyzed by Bismuth (III) Triflate

Xiao-hua CAI, Hui GUO, Bing XIE


Bismuth (III) triflate was found to be effective Lewis acid catalyst for direct alkylative Passerini reaction of
aldehydes, isocyanides, and aliphatic alcohols. In the present reaction, α-unsaturated and aromatic aldehydes used as
substrates produced the corresponding α-alkoxy amide products in good yield.

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International Journal of Chemistry   ISSN 1916-9698 (Print)   ISSN 1916-9701 (Online)

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